丙烯与溴化氢亚新体育的马氏加成(зғҜзғғдё

丙烯与溴化氢的马氏加成

亚新体育иҝҷдёӘжҲ‘们д№ҰдёҠеҮәзҺ°дәҶпјҢеҰӮжһңжІЎжңүиҝҮж°§еҢ–зү©еӯҳеңЁпјҢжәҙеҠеңЁдёҺиӢҜеҹәеҠиҝһзҡ„зўідёҠпјӣеҰӮжһңжңүиҝҮж°§еҢ–зү©пјҢйӮЈд№Ҳж°ўеҠеңЁдёҺиӢҜеҹәзӣёиҝһзҡ„зўідёҠгҖӮ丙烯与溴化氢亚新体育的马氏加成(зғҜзғғдёҺжәҙеҢ–ж°ўеҠ жҲҗеҸҚеә”жқЎд»¶)й«ҳеӨ„иЎҖжё…дёӯдә”зұ»Igеҗ«йҮҸз”ұе°‘еҲ°еӨҡзҡ„йЎәеәҸжҳҜз”өеӯҗе•ҶеҠЎйЎ№зӣ®и®ҫи®Ўе‘ҲзҺ°еӨҡе…ғеҢ–,е®үиЈ…жЎҲзҘһе’ҢеҠЁжҖҒеҢ–зҡ„зү№зӮ№гҖӮз»ҙжҠӨж•°еӯҰжЁЎеһӢдё»иҰҒжңүе“ӘдәӣжЁЎеһӢ?жӢҶйҷӨйҮ‘иһҚдҪ“зі»дёӯеҢ…жӢ¬йҮ‘иһҚжңәжһ„

CH2=CHCH3+H2>=CHCH3+HBr>жҲ–CH2=CHCH3+HBr>

дҪеҘҪ亚新体育пјҢдҪиҜҙзҡ„дёүж°ҜдёҷзғҜжҳҜCCl3-CH=CH2еҗ—пјҹиҝҷдёӘеҸҚ马ж°Ҹзҡ„еҺҹеӣжҳҜдёүж°Ҝз”ІеҹәжҳҜејәеҗёз”өеӯҗеҹәпјҢжүҖд»ҘеҸҢй”®дёҠйқўзҡ„з”өеӯҗдә‘дјҡеҗ‘дёӯй—ҙзҡ„зўіеҺҹеӯҗеҒҸ移пјҢеҚідёӯй—ҙзўіеҺҹеӯҗзӣёеҜ№еҸҰдёҖдёӘеҸҢй”®зўіеҺҹеӯҗ

丙烯与溴化氢亚新体育的马氏加成(зғҜзғғдёҺжәҙеҢ–ж°ўеҠ жҲҗеҸҚеә”жқЎд»¶)


зғҜзғғдёҺжәҙеҢ–ж°ўеҠ жҲҗеҸҚеә”жқЎд»¶


дёҷзғҜ(CH3-CH=CH2)з”ұдәҺе…·жңүзғҜзғғз»“жһ„,еӣжӯӨеҢ–еӯҰжҖ§иҙЁе’Ңд№ҷзғҜдёҖж·,иғҪдёҺеҚӨзҙгҖҒеҚӨеҢ–ж°ўгҖҒH2OгҖҒH2SO4гҖҒHOClзӯүиө·еҠжҲҗеҸҚеә”,д№ҹиғҪиҝӣиЎҢж°§еҢ–е’ҢиҒҡеҗҲеҸҚеә”гҖӮдҪҶдёҷзғҜдёҺжһҒжҖ§иҜ•еүӮеҠжҲҗж—¶

зӯ”жЎҲдёҷзғҜдёҺжәҙеҢ–ж°ўиғҪеҸ‘з”ҹеҠжҲҗеҸҚеә”,е…¶дә§зү©зҡ„з»“жһ„з®ҖејҸжҳҜ,еҗҚз§°жҳҜ2-жәҙдёҷзғ·.зӣёе…іжҺЁиҚҗ1дёҷзғҜдёҺжәҙеҢ–ж°ўиғҪеҸ‘з”ҹеҸҚеә”,е…¶дә§зү©зҡ„з»“жһ„з®ҖејҸжҳҜеҗҚз§°жҳҜеҸҚйҰҲ收и—Ҹ

дёҷзғҜпјҢеӣдёәдёҷзғҜзҡ„еҸҢй”®дҪҚзҪ®дёҚеҜ№з§°пјҢдёӨиҫ№з”өжҖ§е·®еҲ«жӣҙеӨ§пјҢжӣҙжҳ“еҠжҲҗгҖӮпјҲеҘҪеғҸеҸ«й©¬ж°Ҹ规еҲҷпјү

丙烯与溴化氢亚新体育的马氏加成(зғҜзғғдёҺжәҙеҢ–ж°ўеҠ жҲҗеҸҚеә”жқЎд»¶)


10.дёҷзғҜдёҺжәҙеҢ–ж°ўеҸ‘з”ҹеҠжҲҗеҸҚеә”еҸҜеҲҶдёәдёӨжӯҘ:第дёҖжӯҘеҸҚеә”зҡ„иғҪйҮҸеҸҳеҢ–иҝҮзЁӢеҰӮеӣҫжүҖзӨә,еҫ—еҲ°зҡ„дёӯй—ҙдҪ“еҶҚдёҺжәҙзҰ»еӯҗз»“еҗҲжҲҗжәҙеҶ…зғ·еҚідёә第дәҢжӯҘеҸҚеә”(第дәҢжӯҘеҸҚеә”иҝ…йҖҹдё”дёӨдёӘж–№еҗ‘зҡ„иғҪйҮҸеҸҳеҢ–еҹәжң¬зӣёеҗҢ丙烯与溴化氢亚新体育的马氏加成(зғҜзғғдёҺжәҙеҢ–ж°ўеҠ жҲҗеҸҚеә”жқЎд»¶)вҖңжң亚新体育үжңәеҢ–еӯҰ马ж°Ҹ规еҲҷвҖқзӣёе…ізҡ„иҜ•йўҳ32.еҶҷеҮәдёӢеҲ—жңүжңәеҸҚеә”зҡ„еҢ–еӯҰж–№зЁӢејҸ(1)з”ұиӢҜд№ҷзғҜеҲ¶еҸ–иҒҡиӢҜд№ҷзғҜвҲACB(2)дёҷзғҜдёҺжәҙеҢ–ж°ўжҢү照马ж°Ҹ规еҲҷеҸ‘з”ҹеҠжҲҗеҸҚеә”CH2=CHCH3+HBrвҶ’CH3